Synthesis and coordination ability of a partially silicon based crown ether.
نویسندگان
چکیده
The first hybrid crown ether with two adjacent disilane fragments was synthesized through reaction of O(Si2Me4Cl)2 (3) with O(C2H4OH)2. By means of DFT calculations, the complexation ability of 1,2,4,5-tetrasila[12]crown-4 (7) towards Li+ was determined to be considerably higher compared to [12]crown-4.
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 90 شماره
صفحات -
تاریخ انتشار 2016